Useful and Harmful Effects of Polyhalogen Compounds

CompoundUseful effects / UsesHarmful effects
Dichloromethane (CH₂Cl₂)• Used as a solvent for paints, varnishes and adhesives.
• Used in paint removers and as a solvent in pharmaceutical industries.
• Its vapours can affect the central nervous system.
• Prolonged exposure can be harmful to health.
Chloroform (CHCl₃)• Used as a solvent for fats, oils, alkaloids, iodine, etc.
• Earlier used as an anaesthetic.
• In air/light, it can form phosgene (COCl₂), a highly poisonous gas.
• Therefore, it is stored in dark bottles with a little ethanol.
Tetrachloromethane / Carbon tetrachloride (CCl₄)• Used as a solvent for fats, oils and resins.
• Earlier used in fire extinguishers.
• Toxic to the liver and kidneys.
• Harmful to the ozone layer.
Freons (CFCs)• Used as refrigerants in refrigerators and air-conditioners.
• Used as propellants in aerosol sprays.
• Cause depletion of the ozone layer.
• UV radiation reaching Earth increases due to ozone depletion.
DDT• Powerful insecticide.
• Used to control mosquitoes and agricultural pests.
• Non-biodegradable, so it persists in the environment.
• Accumulates in organisms and undergoes biomagnification.
• Can harm birds and other wildlife.
CompoundUseful effects / UsesHarmful effects
Iodoform (CHI₃)• Used as an antiseptic and disinfectant.
• Historically used for dressing wounds because of its antimicrobial action.
• Has a characteristic yellow colour and smell.
• Can cause skin irritation on prolonged contact.
• Its vapours can irritate the eyes and respiratory tract.
• Excessive exposure can be harmful.

Molecular Formula of All Compounds

CompoundMolecular Formula
DichloromethaneCH₂Cl₂
ChloroformCHCl₃
IodoformCHI₃
Carbon tetrachloride / TetrachloromethaneCCl₄
Freons (CFCs)CCl₂F₂ (Freon-12, common example)
DDTC₁₄H₉Cl₅

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