Wave Nature of Matter (de Broglie Hypothesis) – CBSE Class 12 Notes

Dual Nature of Light

  • Light exhibits both wave nature and particle nature.
  • Wave nature is observed in:
    • Interference
    • Diffraction
    • Polarisation
  • Particle nature is observed in:
    • Photoelectric effect
    • Compton effect

de Broglie Hypothesis

  • In 1924, French physicist Louis de Broglie proposed that moving material particles also possess wave nature.
  • According to him, if light (energy) shows dual nature, then matter should also exhibit dual nature.

de Broglie Wavelength

The wavelength associated with a moving particle is called the de Broglie wavelength.

Formula

λ=hp\boxed{\lambda=\frac{h}{p}}

Since,p=mvp=mv

therefore,λ=hmv\boxed{\lambda=\frac{h}{mv}}

where:

  • λ\lambda = de Broglie wavelength
  • hh = Planck’s constant (6.626×1034J s)(6.626 \times 10^{-34}\,\text{J s})(6.626×10−34J s)
  • pp = Momentum of particle
  • mm = Mass of particle
  • vv= Velocity of particle

Significance of de Broglie Equation

  • It establishes the dual nature of matter.
  • The left side (λ\lambdaλ) represents the wave property.
  • The right side (mvmvmv) represents the particle property.

de Broglie Wavelength of a Photon

For a photon,p=hνcp=\frac{h\nu}{c}

Substituting in the de Broglie equation,λ=hp=hchν=cν\lambda=\frac{h}{p} =\frac{hc}{h\nu} =\frac{c}{\nu}

Since,λ=cν\boxed{\lambda=\frac{c}{\nu}}

Thus, the de Broglie wavelength of a photon is the same as the wavelength of electromagnetic radiation.


Dependence of de Broglie Wavelength

Fromλ=hmv\lambda=\frac{h}{mv}

  • Mass increases → Wavelength decreases
  • Velocity increases → Wavelength decreases

Thus,

  • Heavy particles have very small de Broglie wavelength.
  • Light particles have larger de Broglie wavelength.

Why Don’t We Observe Wave Nature of Everyday Objects?

  • Macroscopic objects have very large mass, so their de Broglie wavelength is extremely small.
  • Such small wavelengths cannot be detected experimentally.
  • Therefore, everyday objects do not show observable wave nature.

Wave Nature of Microscopic Particles

  • Electrons, protons, neutrons and other subatomic particles have small mass.
  • Their de Broglie wavelength is measurable.
  • Hence, they exhibit wave properties such as diffraction and interference.

CBSE Important Points

  • Proposed by Louis de Broglie (1924).
  • Every moving particle has an associated matter wave.
  • Matter waves are called de Broglie waves.
  • De Broglie wavelength is: λ=hmv\boxed{\lambda=\frac{h}{mv}}
  • Higher momentum → Smaller wavelength.
  • Wave nature is significant only for microscopic particles.
  • The de Broglie wavelength of a photon is equal to the wavelength of the corresponding electromagnetic radiation.

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