Quick Revision
- 1870 → Crookes discovered cathode rays.
- 1879 → Crookes proposed negatively charged particles.
- 1895 → Roentgen discovered X-rays.
- 1897 → J. J. Thomson discovered electron and measured e/m ratio.
Cathode Rays and Electron Discovery – Key Points
- Cathode ray particles travel at speeds of about 0.1–0.2 times the speed of light.
- The accepted value of the charge-to-mass ratio (e/m) is:
1.76×1011 C kg−1 - The value of e/m is independent of:
- The cathode material used.
- The gas present in the discharge tube.
- This showed that cathode ray particles are universal in nature.
- In 1887, it was observed that some metals emit negatively charged particles when exposed to ultraviolet light (photoelectric effect).
- Certain metals also emit negatively charged particles when heated to high temperatures (thermionic emission).
- The e/m value of these particles was found to be the same as that of cathode ray particles.
- Therefore, all these particles were concluded to be identical in nature.
- In 1897, J. J. Thomson named these particles electrons.
- Thomson proposed that electrons are fundamental constituents of matter.
- For his work on conduction of electricity through gases and discovery of the electron, Thomson received the Nobel Prize in Physics (1906).
- In 1913, Robert A. Millikan performed the famous oil-drop experiment.
- Millikan measured the charge of an electron as:
e=1.602×10−19 C - He found that the charge on oil drops was always an integral multiple of the elementary charge.
- This established that electric charge is quantized.
- Using the values of e and e/m, the mass of an electron was calculated:
m=9.11×10−31 kg
Important Years for NEET/JEE
- 1887 → Photoelectric emission observed.
- 1897 → J. J. Thomson discovered and named the electron.
- 1906 → Thomson received Nobel Prize.
- 1913 → Millikan’s oil-drop experiment.
- (e = 1.602 \times 10^{-19}) C
- (e/m = 1.76 \times 10^{11}) C kg⁻¹
- (m = 9.11 \times 10^{-31}) kg.