- Law: Properties of elements are a periodic function of their atomic masses
- Elements arranged in increasing atomic mass
- Similar properties appear at regular intervals → periodicity
🧪 Key Features
1. Groups & Periods
- Vertical columns → Groups (I to VIII)
- Horizontal rows → Periods
- Elements in same group → similar valency & chemical properties
2. Subgroups (A & B)
- Each group divided into:
- A (main group) → normal elements
- B (transition elements) → less regular properties
3. Gaps for Undiscovered Elements ⭐ (VERY IMPORTANT)
- Mendeleev left blank spaces for unknown elements
- Predicted their properties accurately
Example:- Eka-aluminium → Gallium
- Eka-silicon → Germanium
4. Correction of Atomic Mass
- If element didn’t fit → atomic mass was corrected
- Example: Tellurium–Iodine anomaly handled by placement based on properties
5. Periodicity Trend
- Properties repeat due to similar valence shell configuration (not known then)
⚠️ Limitations (High-weightage for exams)
1. Hydrogen Position ❓
- Resembles Group 1 and Group 17 → no fixed position
2. Isotopes Problem
- Isotopes have same properties but different masses
- Could not be placed properly
3. Increasing Atomic Mass Order Violations
- Example:
- Argon (39.9) before Potassium (39.1)
- Order violated to maintain chemical similarity
4. No Explanation of Periodicity
- Reason (electronic configuration) was unknown
5. Lanthanides & Actinides
- No proper place in table