Mendeleev’s Periodic Table – Core Concept

  • Law: Properties of elements are a periodic function of their atomic masses
  • Elements arranged in increasing atomic mass
  • Similar properties appear at regular intervals → periodicity

🧪 Key Features

1. Groups & Periods

  • Vertical columns → Groups (I to VIII)
  • Horizontal rows → Periods
  • Elements in same group → similar valency & chemical properties

2. Subgroups (A & B)

  • Each group divided into:
    • A (main group) → normal elements
    • B (transition elements) → less regular properties

3. Gaps for Undiscovered Elements ⭐ (VERY IMPORTANT)

  • Mendeleev left blank spaces for unknown elements
  • Predicted their properties accurately
    Example:
    • Eka-aluminium → Gallium
    • Eka-silicon → Germanium

4. Correction of Atomic Mass

  • If element didn’t fit → atomic mass was corrected
    • Example: Tellurium–Iodine anomaly handled by placement based on properties

5. Periodicity Trend

  • Properties repeat due to similar valence shell configuration (not known then)

⚠️ Limitations (High-weightage for exams)

1. Hydrogen Position ❓

  • Resembles Group 1 and Group 17 → no fixed position

2. Isotopes Problem

  • Isotopes have same properties but different masses
  • Could not be placed properly

3. Increasing Atomic Mass Order Violations

  • Example:
    • Argon (39.9) before Potassium (39.1)
  • Order violated to maintain chemical similarity

4. No Explanation of Periodicity

  • Reason (electronic configuration) was unknown

5. Lanthanides & Actinides

  • No proper place in table

Leave a comment